Tannic Acid as a Functional Crosslinker in Polymer Systems
An environmentally friendly and inexpensive thermosetting polymeric composition utilizes tannic acid as a sustainable hardener for high-performance epoxy applications, including fire retardancy.
Current epoxy crosslinkers are amine-based, which are not environmentally friendly. Upon epoxy degradation, the chemicals leech out into the environment. Tannic acid is a well-known, naturally occurring polyphenolic compound used in antioxidants and chelating agents. The study of tannic acid's use in a wide variety of polymer systems as a flame retardant additive is extensive; however, its use as a hardener/cross-linker in epoxy lacks research.
Researchers at Purdue University have developed a thermosetting polymeric composition by crosslinking epoxy by using tannic acid as the hardener. Tannic acid is a more sustainable crosslinker, has less environmental impact, and is inexpensive given it is a byproduct from the papermaking process. This composition has a high glass transition temperature and extended pot-life. This composition also allows for tannic acid's use as functional system to prepare formulations with other properties such as fire retardancy.
Advantages:
-Environmentally friendly
-Inexpensive
-High glass transition temperature
Potential Applications:
-High performance epoxy
-Flame retardant
TRL: 3
Intellectual Property:
Provisional-Patent, 2017-03-01, United States | NATL-Patent, 2018-02-27, Europe | NATL-Patent, 2018-02-27, Canada | PCT-Patent, 2018-02-27, WO | NATL-Patent, 2019-08-19, United States
Keywords: tannic acid, epoxy hardener, sustainable crosslinker, environmentally friendly epoxy, high glass transition temperature, extended pot-life, fire retardancy, thermosetting polymeric composition, polyphenolic compound, flame retardant additive, Biotechnology, Chemistry and Chemical Analysis, Compounds, Epoxy, Flame Retardants, Materials and Manufacturing, Polymers